Ready-Mixed Concrete

Ready-Mixed Concrete Material Safety Data Sheet

Product Ready-Mixed Concrete
Synonyms Ready Mix Concrete, Portland Cement Concrete, Concrete, Pervious Concrete, Self-Consolidating Concrete, Flowable Fill
Use Concrete is widely used as a structural component in construction.
Product Manufacturer Dolese Bros. Co. 20 N.W. 13th Oklahoma City, OK 73103 Phone: 405‐235‐2311 www.dolese.com
GHS LABEL ELEMENTS  
Signal Word Danger
Hazard statement Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. May cause an allergic skin reaction.
Prevention
  • Wash thoroughly after handling.
  • Wear protective gloves/protective clothing/eye protection/face protection.
  • Obtain special instructions before use.
  • Do not handle until all safety precautions have been read and understood.
  • Do not breathe dust.
Response If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor. If on skin (or hair): Rinse skin with water/shower. Wash contaminated clothing before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses if worn. Continue rinsing. If irritation persists, seek medical attention.
Disposal Dispose in accordance with local/regional/international regulations.
Component Information / Information on Non ‐ Hazardous Components
Component Percent
Aggregates 36 ‐ 92
Cement, portland, chemicals 2 ‐ 26
Ashes, residues 0 - 25
Water 6 - 13
Quartz 5 - 13
 
General Product Information   Trace Elements: Ready-mixed concrete is made from materials mined from the earth. Trace amounts of naturally occurring elements might be detected during chemical analysis of these materials.
Inhalation Remove to fresh air. Seek medical help if coughing and other symptoms do not subside. (Inhalation of gross amounts of the dry ingredients in Ready-mixed concrete requires immediate medical attention.)
Skin contact Wash skin with cool water and pH ‐ neutral soap or a mild detergent intended for use on skin. Seek medical treatment if irritation is caused by prolonged exposure to wet concrete, liquids from wet concrete products, or prolonged wet skin exposure to the dry ingredients in Ready ‐ Mix concrete.
Eye contact Immediately flush eyes thoroughly with water. Continue flushing eye for at least 15 minutes, including under eye lids, to remove all particles. Call physician if irritation persists.
Ingestion Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately.
Suitable extinguishing media Non‐flammable. Use appropriate extinguishing media for surrounding fire.
Unsuitable extinguishing media None known
General Fire Hazards See Section 9 for Flammability Properties. Non ‐ combustible.
Hazardous Combustion Products None
Firefighting equipment/instructions No Specific precautions.
Recovery and Neutralization Stop the flow of material, if this is without risk.
Materials and methods for containment and clean-up Collect dry material using a scoop. Avoid actions that cause dust to become airborne. Avoid inhalation of dust and contact with skin. Scrape up wet material and place in an appropriate container. Allow the material to harden before disposal.
Emergency Measures Keep unnecessary personnel away.
Personal precautions and emergency procedures Wear appropriate protective equipment and clothing during clean‐up of materials that contain or may liberate Limestone dust.
Prevention of Secondary Hazards None
Environmental Precautions Avoid discharge of fine particulate matter into drains or water courses.
Handling Procedures Avoid contact with eyes and skin. Promptly remove clothing which is wet with concrete and launder before reuse. Wash thoroughly after exposure to wet concrete mixtures.
Incompatibilities Wet ready-mixed concrete is alkaline. As such it is incompatible with acids, ammonium salts and aluminum metal.
Engineering Measures Use local exhaust or general dilution ventilation to control exposure within applicable limits.
Personal Protective Equipment: Respiratory Use local or general ventilation to control exposures below applicable exposure limits. NIOSH or MSHA approved particulate filter respirators should be used in the context of respiratory protection program meeting the requirements of the OSHA respiratory protection standard [29 CFR 1910.134] to control exposures when ventilation or other controls are inadequate or discomfort or irritation is experienced. Use appropriate respirator/filter cartridge selection.
Personal Protective Equipment: Hands Where prolonged exposure to unhardened concrete products might occur, wear impervious gloves to eliminate skin contact. Periodically wash areas contacted by wet cement or its dry ingredients with a pH neutral soap and water. Wash again at the end of the work. If irritation persists, immediately wash the affected area and seek treatment.
Personal Protective Equipment: Eyes When engaged in activities where wet concrete or its dry ingredients could contact the eye, wear safety glasses with side shields or goggles.
Personal Protective Equipment: Skin and Body Where prolonged exposure to unhardened concrete products might occur, wear impervious clothing to eliminate skin contact. Where required, wear boots that are impervious to water to eliminate foot and ankle exposure. If clothing becomes saturated with wet concrete, it should be removed and replaced with clean dry clothing.
 Appearance  Gray granularmixture
 Physical State  Liquid,semi‐solid
 Vapor Pressure  Not Applicable
 Boiling Point  Not Applicable
 Solubility (H2O)  Slightly soluble
 Evaporation Rate  Not Applicable
 Ignition  Non‐Flammable
 Odor  None
 pH  12‐13 (in water)
 Vapor Density  Not Applicable
 Melting Point  Not Applicable
 Specific Gravity  1.70‐3.00
 VOC  Not Determined
 Flash Point  None
Chemical Stability This is a stable material.
Hazardous Reaction Potential Will not occur
Incompatible Products Wet Ready‐Mix concrete is alkaline. As such it is incompatible with acids, ammonium salts and aluminum metal.
Hazardous Decomposition Products Will not spontaneously occur.
Acute Toxicity Wet concrete is not known to be toxic. Toxicity related to major components of concrete: cement, fly ash, and silica sand are negated in wet concrete form. The matrix precludes the inhalation of these constituents which could normally be of an occupational safety concern. The admixture and air entraining agents are sulfonate solutions which are not considered toxic.
Potential Health Effects: Skin Corrosion Property /Stimulativeness Discomfort or pain cannot be relied upon to alert a person to a hazardous skin exposure. Consequently, the only effective means of avoiding skin injury or illness involves minimizing skin contact, particularly contact with wet concrete. Exposed persons may not feel discomfort until hours after the exposure has ended and significant injury has occurred. Exposure during the handling or mixing of the dry ingredients in Ready‐Mix concrete may cause drying of the skin with consequent mild irritation or more significant effects attributable to aggravation of other conditions. Exposure to wet concrete may cause more severe skin effects including thickening, cracking or fissuring of the skin. Prolonged exposure can cause severe skin damage in the form of (caustic) chemical burns.
Potential Health Effects: Eye Critical Damage/ Stimulativeness Exposure to airborne dust during the sawing of hardened concrete or handling/mixing of the dry ingredients in Ready‐Mix concrete may cause immediate or delayed irritation or inflammation. Eye contact by splashes of wet concrete may cause effects ranging from moderate eye irritation to chemical burns. Such exposures require immediate first aid (see Section 4) and medical attention to prevent significant damage to the eye.
Potential Health Effects: Ingestion Although inadvertent ingestion of small quantities of wet concrete or its dry ingredients are not known to be harmful, accidental ingestion of larger quantities can be harmful and requires immediate medical attention.
Potential Health Effects: Inhalation The ingredients in Ready‐Mix concrete contain crystalline silica. Exposure to these ingredients in excess of the applicable TLV or PEL may cause or aggravate other lung conditions. Exposure to the dry ingredients in Ready‐Mix concrete may cause irritation to the moist mucous membranes of the nose, throat, and upper respiratory system.

Carcinogenicity

A: General Product Information May cause cancer. Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease and/or lung cancer. IARC states that crystalline silica in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1).

B: Component Carcinogenicity

Cement, portland, chemicals
ACGIH Not Classifiable as a Human Carcinogen. However, cement contains trace amounts of crystalline silica and hexavalent chromium which are classified by the IARC and NTP as known human carcinogens.
Quartz
ACGIH Suspected Human Carcinogen
NIOSH Potential Occupational Carcinogen
NTP Known Human Carcinogen
IARC Monograph 100C [2012] Crystalline silica in the form of quartz or cristobalite is carcinogenic to humans (Group 1)
Reproductive Toxicity This product is not reported to have any reproductive toxicity effects.
Specified Target Organ General Toxicity: Single Exposure This product is not reported to have any single exposure specific target organ toxicity effects.
Specified Target Organ General Toxicity: Repeated Exposure Causes damage to organs through prolonged or repeated exposure (lungs).
Aspiration Respiratory Organs Hazard This product is not reported to have any aspiration hazards.

Seek information from appropriate regulatory agencies.

Disposal instructions Do not allow fine particulate matter to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with fine particulates. Dispose of contents in accordance with local/regional/national/international regulations.
Hazardous waste code Not regulated.
Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions).
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty packaging materials should be recycled or disposed of in accordance with applicable regulations and practices.

Seek information from appropriate regulatory agencies.

US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200.
ACGIH  American Conference of Governmental Industrial Hygienists 
CFR Code for Federal Regulations 
DOT U.S. Department of Transportation 
HMIS Hazardous Materials Identification System 
IARC  International Agency for Research on Cancer 
MSHA  Mine Safety and Health Administration 
TLV  Threshold Limit Value
NFPA  National Fire Protection Association
NIOSH  National Institute for Occupational Safety and Health
NTP  National Toxicology Program
OSHA  Occupational Safety and Health Administration
PEL  Permissible Exposure Limit
pH  Negative log of hydrogen ion
PPE  Personal Protective Equipment

NFPA/HMIS: Health-1, Flammability-0, Physical Hazard/Reactivity-0

NFPA/HMIS Definitions: 0‐Least, 1‐Slight, 2‐Moderate, 3‐High,

4‐Extreme Protective Equipment: Safety glasses, gloves, impervious clothing, boots

Dolese Bros. Co. (DBC) believes the information contained herein is accurate; however, DBC makes no guarantees with respect to such accuracy and assumes no liability in connection with the use of the information contained herein which is not intended to be and should not be construed as legal advice or as insuring compliance with any federal, state or local laws or regulations. Any party using this product should review all such laws, rules, or regulations prior to use, including but not limited to the United States and Local State regulations.

NO WARRANTY IS MADE, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OTHERWISE.

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